Transport and Magnetic Properties of Ag8Ge1—xMnxTe6 Solid Solutions

The solubility regions of $${\text{A}}{{{\text{g}}}_{8}}{\text{G}}{{{\text{e}}}_{{1 - x}}}{\text{M}}{{{\text{n}}}_{x}}{\text{T}}{{{\text{e}}}_{6}}$$ solid solutions were determined by structural analysis. The nature of sample conductivity was revealed by studying kinetic parameters in the range of 100–600 K. The samples are p-type and have high resistance below the temperature range of 180–220 K. The electrical conductivity in the range of 220–300 K increases according to the Mott rule, and at T > 320 K a semiconductor behavior is observed in samples of all compositions. In the temperature range of 80–750 K, the features of the field dependences of the specific magnetization σm = f(B), as well as the susceptibility of the $${\text{A}}{{{\text{g}}}_{8}}{\text{G}}{{{\text{e}}}_{{1 - x}}}{\text{M}}{{{\text{n}}}_{x}}{\text{T}}{{{\text{e}}}_{6}}$$ composition, were studied. The temperature of the magnetic phase transformation “magnetic order–magnetic disorder” of the composition $${\text{A}}{{{\text{g}}}_{8}}{\text{G}}{{{\text{e}}}_{{1 - x}}}{\text{M}}{{{\text{n}}}_{x}}{\text{T}}{{{\text{e}}}_{6}}$$ was determined.

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Publication Details

Journal
Russian Journal of Inorganic Chemistry
Published
2025-08-09
DOI
https://doi.org/10.1134/s0036023625600601
Primary Topic
Phase-change materials and chalcogenides
Type
article
Field-Weighted Citation Impact
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article

Transport and Magnetic Properties of Ag8Ge1—xMnxTe6 Solid Solutions

V. I. Mityuk, I. Kh. Mammadov, A.M. Zhivulko, А. А. Халилова et al.
Russian Journal of Inorganic Chemistry
Phase-change materials and chalcogenides
article

Transport and Magnetic Properties of Ag8Ge1—xMnxTe6 Solid Solutions

V. I. Mityuk, I. Kh. Mammadov, A.M. Zhivulko, А. А. Халилова, Д. Г. Араслы, R. N. Rahimov, A. S. Kahramanova
article en

Abstract

The solubility regions of $${\text{A}}{{{\text{g}}}_{8}}{\text{G}}{{{\text{e}}}_{{1 - x}}}{\text{M}}{{{\text{n}}}_{x}}{\text{T}}{{{\text{e}}}_{6}}$$ solid solutions were determined by structural analysis. The nature of sample conductivity was revealed by studying kinetic parameters in the range of 100–600 K. The samples are p-type and have high resistance below the temperature range of 180–220 K. The electrical conductivity in the range of 220–300 K increases according to the Mott rule, and at T > 320 K a semiconductor behavior is observed in samples of all compositions. In the temperature range of 80–750 K, the features of the field dependences of the specific magnetization σm = f(B), as well as the susceptibility of the $${\text{A}}{{{\text{g}}}_{8}}{\text{G}}{{{\text{e}}}_{{1 - x}}}{\text{M}}{{{\text{n}}}_{x}}{\text{T}}{{{\text{e}}}_{6}}$$ composition, were studied. The temperature of the magnetic phase transformation “magnetic order–magnetic disorder” of the composition $${\text{A}}{{{\text{g}}}_{8}}{\text{G}}{{{\text{e}}}_{{1 - x}}}{\text{M}}{{{\text{n}}}_{x}}{\text{T}}{{{\text{e}}}_{6}}$$ was determined.

Russian Journal of Inorganic Chemistry
National Academy of Sciences of Belarus (BY), Ministry of Science and Education Republic of Azerbaijan (AZ), Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus (BY), National Aviation Academy (AZ)
Openalex Percentile: Top 85%
Phase-change materials and chalcogenides
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