Mathematical modelling of drying capillary porous media

The evaporation of liquid from within a porous medium is a complicated process involving coupled capillary flow, vapour diffusion and phase change. Different drying behaviour is observed at different stages during the process. Initially, liquid is drawn to the surface by capillary forces, where it evaporates at a near constant rate; thereafter, a drying front recedes into the material, with a slower net evaporation rate. Modelling drying porous media accurately is challenging due to the multitude of relevant spatial and temporal scales, and the large number of constitutive laws required for model closure. Key aspects of the drying process, including the net evaporation rate and the time of the sudden transition between stages, are not well understood or reliably predicted. We derive simplified mathematical models for both stages of this drying process by systematically reducing an averaged continuum multi-phase flow model, using the method of matched asymptotic expansions, in the physically relevant limit of slow vapour diffusion relative to the local evaporation rate (the large-Péclet-number limit). By solving our reduced models, we compute the evolving net evaporation rate, fluid fluxes and saturation profiles, and estimate the transition time to be when the initial constant-rate-period model ceases to be valid. We additionally characterise properties of the constitutive laws that affect the qualitative drying behaviour: the model is shown to exhibit a receding-front period only if the relative permeability for the liquid phase decays sufficiently quickly relative to the blow up in the capillary pressure as the liquid saturation decreases.