Solvent-regulated electro-oxidation of iodide and its electrocatalytic performance towards acetylacetone oxidation
Solvent-regulated iodide electro-oxidation and its electrocatalysis for acetylacetone oxidation are presented. Solvent donor number (DN) and polarity govern iodine species stability, while water in medium-polar solvents with moderate DN enhances electrocatalytic activity, with increased current and unexpected cathodic shift of onset potential, revealing a novel solvent-tuning phenomenon.
Authors
- K. Yang (ORCID: https://orcid.org/0000-0001-5146-7311)
- Z. Ye (ORCID: https://orcid.org/0000-0001-6091-6772)
- Feng Zhu (ORCID: https://orcid.org/0000-0002-7515-3998)
- Wenbin Zhang (ORCID: https://orcid.org/0000-0002-3053-2388)
Institutions
- Yichun University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03902a
- Primary Topic
- Electrochemical Analysis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00