Reactive transverse waves in a near-limit detonation

The reactivity of transverse waves in detonations of methane, oxygen and nitrogen are experimentally assessed using MHz rate schlieren and chemiluminescence imaging. In these highly unstable mixtures, the mode of wave propagation is more complex than what is described by the cellular instability model that is conventionally used for weakly unstable mixtures. Behind the low-speed leading shock in unstable waves, the processed gas remains essentially unreacted until transverse waves reach this region. In highly unstable waves, the transverse waves have a range of reactivity, that is rates of reaction in the flow immediately behind the wave. In this study, we present examples of transverse waves for near-limit detonations and analyse four cases in detail. In some cases, these waves appear to be essentially non-reactive or cause very slow reaction. In other cases, the transverse waves can be highly reactive. In the most extreme example, the transverse wave is propagating at the Chapman–Jouguet speed with a small reaction zone, i.e. a transverse detonation. A reactive oblique shock model is used to approximate the triple-point configuration of this case as a double-Mach reflection, which shows good agreement with the images. The reaction evolution along path lines is analysed using detailed reaction mechanisms and considerations about flow-field unsteadiness. Length scales of the energy release and expansion processes within the reaction zone region are used to explain the observed modes of wave propagation and interaction.