Sol–Gel Synthesized CuFe2O4-Modified Biochar Derived from Tea Waste for Efficient Ni(II) Removal: Adsorption, Regeneration, and ANN Modeling

In the present research, a novel magnetic adsorbent was developed via the sol-gel method by coating CuFe₂O₄ nanoparticles on biochar sourced from brewed tea waste. The synthesized adsorbent was utilized for the removal of Ni(II) ions from aqueous media. The adsorption efficiency of Ni(II) ions was assessed under crucial experimental conditions such as initial solution pH, contact time, adsorbent dosage, and initial Ni(II) concentration. The adsorbent exhibited rapid adsorption kinetics, achieving equilibrium in approximately 15 min, and maintained high efficiency across a wide pH range. Adsorption experiments were conducted for Ni(II) solutions at their natural pH (5.6) to minimize chemical usage and enhance process simplicity. An impressive maximum adsorption capacity of 232.6 mg g^-1 was recorded, outperforming many previously reported adsorbents. Furthermore, desorption studies demonstrated nearly 100% recovery of Ni(II) ions using 1.0 M HCl solution, indicating excellent regeneration potential of the adsorbent. Additionally, the prediction performance of an artificial neural network (ANN) model was evaluated to predict Ni(II) removal efficiency based on experimental variables, showing strong agreement with experimental data. Isotherm and kinetic models were also applied to the data to estimate the adsorption mechanisms. These findings demonstrate the promise of CuFe₂O₄-modified tea waste biochar for sustainable water treatment applications.