Support modification by phosphonic acid ligands controls ethylene hydroformylation on single-atom rhodium sites
Local confinement of the active site, estimated by CO bite angle from CO-DRIFTS, directs hydroformylation of ethylene over phosphonic acid modified Rh 1 /TiO 2 catalysts.
Authors
- Daniel K. Schwartz (ORCID: https://orcid.org/0000-0001-5397-7200)
- J. Will Medlin (ORCID: https://orcid.org/0000-0003-2404-2443)
- Zachary Meduna
Institutions
- University of Colorado Boulder (US)
- University of Colorado System (US)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cy00684h
- Citations
- 2
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- U.S. Department of Energy
- Office of Science
- Basic Energy Sciences
- Chemical Sciences, Geosciences, and Biosciences Division