Constant no more: reevaluating Hammett constants through spin-crossover
The spin-crossover phenomenon helped re-evaluate the existing Hammett constants that incorrectly classify electron-withdrawing and electron-donating groups to explain and predict magnetic behaviours, chemical reactivity and beyond.
Authors
- Dmitry Yu. Aleshin
- Igor A. Nikovskiy (ORCID: https://orcid.org/0000-0001-9594-823X)
- Алексей А. Анисимов (ORCID: https://orcid.org/0000-0001-5097-5584)
- Yulia Vladimirovna Nelyubina (ORCID: https://orcid.org/0000-0002-9121-0040)
- Valentin V. Novikov (ORCID: https://orcid.org/0000-0002-0225-0594)
Institutions
- A. N. Nesmeyanov Institute of Organoelement Compounds (RU)
- NS Kurnakova Institute of General and Inorganic Chemistry (RU)
- Institut de Nanociència i Nanotecnologia de la Universitat de Barcelona
- Universitat de Barcelona (ES)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi01184a
- Citations
- 1
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.43