On metal–organic framework isomers, and the SF<sub>6</sub> sorption and fluorescence of an In and a Zr MOF with a tritopic linker
The concept of framework isomers by network topology analysis is illustrated by a new rod-MOF isomer of In<sup>3+</sup> and the tritopic linker 4,4',4''-(benzene-1,3,5-triyl-tris(oxy))tribenzoic acid (H<sub>3</sub>bttb), CTH-41, with a unique 3- and 4-connected net different from 437-MOF. CTH-41 shows affinity for SF<sub>6</sub> with a Langmuir area of 1587 m<sup>2</sup> g<sup>-1</sup> while the new Zr<sup>4+</sup> dot-MOF with the same linker [Zr<sub>6</sub>(bttb)<sub>4</sub>(O)<sub>4</sub>(OH)<sub>4</sub>] CTH-42, forms the 3-, 12-connected llj-net based on a different conformation of the flexible bttb linker.
Authors
- Joakim Andréasson (ORCID: https://orcid.org/0000-0003-4695-7943)
- Ocean Cheung (ORCID: https://orcid.org/0000-0002-4072-4324)
- Zhejian Cao
- Lars Öhrström (ORCID: https://orcid.org/0000-0002-6420-2141)
- Michelle Åhlén (ORCID: https://orcid.org/0000-0002-1587-8073)
- Francoise M. Amombo Noa
- Hao Li (ORCID: https://orcid.org/0000-0001-6946-4362)
Institutions
- Uppsala University (SE)
- Catholic University of Central Africa (CM)
- Chalmers University of Technology (SE)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02180d
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00