Optimization of the Composition of a Thermally Resistant Dielectric Organosilicate Coating Based on Ladder Polymer Polyphenylsilsesquioxane

This article presents the results of a study on protective, dielectric, and thermally resistant organosilicate coatings (OSCs) based on a ladder polymer, polyphenylsilsesquioxane (PPSQ), which is used as a film-forming agent. For the first time, a classical approach is employed to calculate the formulations of pigmented coatings in relation to organosilicate compositions (OSComps). The average viscosity molecular weight of the selected film-forming agent PPSQ is determined. The developed coatings exhibit high thermal resistance up to 420°C while maintaining the necessary physicomechanical and electrophysical properties.

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Publication Details

Journal
Glass Physics and Chemistry
Published
2025-04-01
DOI
https://doi.org/10.1134/s1087659625600164
Primary Topic
Silicone and Siloxane Chemistry
Type
article
Field-Weighted Citation Impact
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article

Optimization of the Composition of a Thermally Resistant Dielectric Organosilicate Coating Based on Ladder Polymer Polyphenylsilsesquioxane

С Н Степин, V. I. Voshchikov, Gennadii Sokolov, T. V. Khamova et al.
Glass Physics and Chemistry
Silicone and Siloxane Chemistry
article

Optimization of the Composition of a Thermally Resistant Dielectric Organosilicate Coating Based on Ladder Polymer Polyphenylsilsesquioxane

С Н Степин, V. I. Voshchikov, Gennadii Sokolov, T. V. Khamova, L. N. Krasilnikova, O. A. Shilova, А. Г. Иванова, Ya. A. Khamidulin
article en

Abstract

This article presents the results of a study on protective, dielectric, and thermally resistant organosilicate coatings (OSCs) based on a ladder polymer, polyphenylsilsesquioxane (PPSQ), which is used as a film-forming agent. For the first time, a classical approach is employed to calculate the formulations of pigmented coatings in relation to organosilicate compositions (OSComps). The average viscosity molecular weight of the selected film-forming agent PPSQ is determined. The developed coatings exhibit high thermal resistance up to 420°C while maintaining the necessary physicomechanical and electrophysical properties.

Glass Physics and ChemistryVol. 51(2)
Saint Petersburg State Electrotechnical University (RU), Petersburg Nuclear Physics Institute (RU), Institute of Chemistry of Silicates named after I.V. Grebenshchikov (RU), Kazan State Technological University (RU)
Openalex Percentile: Top 85%
Silicone and Siloxane Chemistry
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Optimization of the Composition of a Thermally Resistant Dielectric Organosilicate Coating Based on Ladder Polymer Polyphenylsilsesquioxane — С Н Степин, V. I. Voshchikov, et al. · Glass Physics and Chemistry (2025) | TGRS Research Map | TGRS