Intermolecular exchange interaction in bis-(phenoxy Schiff base) Co( <scp>ii</scp> ) complexes: an in-depth insight into the magneto-structural nature of single-molecule magnets
SC-XRD, multifrequency EPR, SQUID, DFT, and ab initio methods reveal exchange coupling and polyhedral distortion shaping the performance of pseudotetrahedral Co( ii ) single-ion magnets.
Authors
- Mercedes Kukułka (ORCID: https://orcid.org/0000-0002-0918-6097)
- Mariusz P. Mitoraj (ORCID: https://orcid.org/0000-0001-5359-9107)
- Damir A. Safin (ORCID: https://orcid.org/0000-0002-9080-7072)
- Michael Bolte (ORCID: https://orcid.org/0000-0001-5296-6251)
- Elizaveta V. Panova (ORCID: https://orcid.org/0009-0002-0379-2296)
- Thomas Lohmiller (ORCID: https://orcid.org/0000-0003-0373-1506)
- Matvey V. Fedin (ORCID: https://orcid.org/0000-0002-0537-5755)
- Radovan Herchel (ORCID: https://orcid.org/0000-0001-8262-4666)
- Olga Minakova (ORCID: https://orcid.org/0000-0001-9356-2325)
- K. Holldack (ORCID: https://orcid.org/0000-0003-3931-3971)
- Jędrzej Kobylarczyk (ORCID: https://orcid.org/0000-0002-1745-3562)
- Robert Podgajny (ORCID: https://orcid.org/0000-0001-7457-6799)
- Sergey L. Veber (ORCID: https://orcid.org/0000-0002-5445-3713)
Institutions
- Goethe University Frankfurt (DE)
- Jagiellonian University (PL)
- Ural Federal University (RU)
- Novosibirsk State University (RU)
- Helmholtz-Zentrum Berlin für Materialien und Energie (DE)
- University of Tyumen (RU)
- Western Caspian University (AZ)
- Institute of Nuclear Physics, Polish Academy of Sciences (PL)
- International Tomography Center (RU)
- Palacký University Olomouc (CZ)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00955c
- Citations
- 3
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 1.28
Funders
- Deutsche Forschungsgemeinschaft
- Russian Science Foundation
- Univerzita Palackého v Olomouci