Chiral environment effects on the dynamics of a central chiral molecule

In this work, we develop a system plus environment approach for interacting chiral molecules under a quantum-classical description of the spin-spin model using a Caldeira-Leggett-like coupling. After presenting the interacting model, we show that a long-ranged parity-nonconserving interaction, encoded within a nonlinear Schr"odinger equation, produces an energy difference between the two enantiomers of the central chiral molecule when it interacts with a chiral environment. Three examples of such interactions are considered, with particular focus on ${Z}^{0}$-photon vacuum polarization. Finally, we reveal a chirality transmission effect phenomenon, where the time-averaged population difference of the central molecule is amplified when the chiral asymmetry of the environment is considered.

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Publication Details

Journal
Physical review. A/Physical review, A
Published
2025-07-30
DOI
https://doi.org/10.1103/x577-1nzd
Citations
1
Primary Topic
Molecular spectroscopy and chirality
Type
article
Field-Weighted Citation Impact
0.76

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article

Chiral environment effects on the dynamics of a central chiral molecule

S. Miret‐Artés, Pedro Bargueño, Daniel Martínez-Gil
1 citations
Physical review. A/Physical review, A
Molecular spectroscopy and chirality
0.76
article

Chiral environment effects on the dynamics of a central chiral molecule

S. Miret‐Artés, Pedro Bargueño, Daniel Martínez-Gil
article en
1 citations

Abstract

In this work, we develop a system plus environment approach for interacting chiral molecules under a quantum-classical description of the spin-spin model using a Caldeira-Leggett-like coupling. After presenting the interacting model, we show that a long-ranged parity-nonconserving interaction, encoded within a nonlinear Schr\"odinger equation, produces an energy difference between the two enantiomers of the central chiral molecule when it interacts with a chiral environment. Three examples of such interactions are considered, with particular focus on ${Z}^{0}$-photon vacuum polarization. Finally, we reveal a chirality transmission effect phenomenon, where the time-averaged population difference of the central molecule is amplified when the chiral asymmetry of the environment is considered.

Physical review. A/Physical review, AVol. 112(2)
University of Alicante (ES), Instituto de Física Fundamental (ES)
Ministerio de Ciencia, Innovación y Universidades, Generalitat Valenciana
Openalex Percentile: Top 27%
Molecular spectroscopy and chirality
0.76
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