Atroposelective [5 + 5] formation of benzo[ <i>c</i> ]chromenone and phenanthridinone by carbene organocatalysis
An atroposelective [5 + 5] annulation strategy for synthesizing chromenones and phenanthridinones via carbene organocatalysis has been developed. The method enables the efficient construction of axially chiral biaryls with gradient rotation barriers.
Authors
- Kejun Lin (ORCID: https://orcid.org/0000-0003-3634-4617)
- Ke Xu (ORCID: https://orcid.org/0000-0002-5293-2411)
- Jing Zeng (ORCID: https://orcid.org/0000-0001-9116-9861)
- Tingshun Zhu (ORCID: https://orcid.org/0000-0002-5757-9696)
- Jiayi Zhao
Institutions
- Sun Yat-sen University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00986c
- Primary Topic
- Axial and Atropisomeric Chirality Synthesis
- Type
- article
- Field-Weighted Citation Impact
- 0.00