Accessing phosphonioacetylide chemistry: isolable alkali metal precursors for rod-shaped carbon donor complexes
The high reactivity of a sterically accessible phosphonioacetylide was tamed via alkali metal coordination. The resulting complexes are precursors for introducing the rod-shaped, strongly electron-donating ligand into transition metal complexes.
Authors
- Stephan Hohloch (ORCID: https://orcid.org/0000-0002-5353-0801)
- Klaus Wurst (ORCID: https://orcid.org/0000-0002-8774-9051)
- Fabian Dielmann (ORCID: https://orcid.org/0000-0002-7025-5450)
- Pawel Löwe (ORCID: https://orcid.org/0000-0003-2275-552X)
- Franka Brylak (ORCID: https://orcid.org/0000-0003-1590-9324)
Institutions
- Universität Innsbruck (AT)
- University of Münster (DE)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi01286d
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Deutsche Forschungsgemeinschaft
- Technische Universität München
- Universität Innsbruck