Flexible Ag2Se-based thin-film thermoelectrics for sustainable energy harvesting and cooling

The high cost and complexity of fabrication limit the large-scale application of flexible inorganic thermoelectric materials. Currently, Bi₂Te₃-based materials are the only commercially viable option, but the inclusion of Te significantly increases production costs. This study presents a simple and cost-effective method for fabricating flexible Ag₂Se films, employing a combination of solvothermal synthesis, screen printing, and spark plasma sintering. The incorporation of a small amount of Te improves film density and facilitates Te diffusion doping, leading to Ag₂Se films with a high power factor of 25.7 μW cm^-1 K^-2 and a figure of merit (ZT) of 1.06 at 303 K. These films exhibit excellent flexibility, retaining 96% of their performance after 1000 bending cycles at a 5 mm bending radius. Additionally, we design a flexible thermoelectric device featuring a triangular p-n junction structure based on these films. This device achieves a normalized power density of 4.8 μW cm^-2 K^-2 at a temperature difference of 20 K and a maximum cooling of 29.8 K with an input current of 92.4 mA. These findings highlight the potential of this fabrication method for developing thermoelectric materials and devices for energy harvesting and cooling applications.