Invariance of Energy Exchange Rates for Light-Dressed Systems

Light-driven matter can exhibit electronic and optical properties qualitatively distinct from those observed at equilibrium. We demonstrate that while strong driving can tune the absorption properties, the energy exchange rate of any light-dressed system remains invariant compared to its bare counterpart. This invariance is evidenced experimentally by the vanishing integrated area of the transient absorption spectrum. We present a general theory alongside experimental results obtained from halide perovskite nanocrystals under strong off-resonance driving. This unexpected result provides useful insights into the optical properties of matter that is driven far from equilibrium.

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Publication Details

Journal
The Journal of Physical Chemistry Letters
Published
2025-08-14
DOI
https://doi.org/10.1021/acs.jpclett.5c01663
Primary Topic
Strong Light-Matter Interactions
Type
article
Field-Weighted Citation Impact
0.00

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article

Invariance of Energy Exchange Rates for Light-Dressed Systems

Yujie Jiao, Siying Peng, Bing Gu
The Journal of Physical Chemistry Letters
Strong Light-Matter Interactions
article

Invariance of Energy Exchange Rates for Light-Dressed Systems

Yujie Jiao, Siying Peng, Bing Gu
article en

Abstract

Light-driven matter can exhibit electronic and optical properties qualitatively distinct from those observed at equilibrium. We demonstrate that while strong driving can tune the absorption properties, the energy exchange rate of any light-dressed system remains invariant compared to its bare counterpart. This invariance is evidenced experimentally by the vanishing integrated area of the transient absorption spectrum. We present a general theory alongside experimental results obtained from halide perovskite nanocrystals under strong off-resonance driving. This unexpected result provides useful insights into the optical properties of matter that is driven far from equilibrium.

The Journal of Physical Chemistry LettersVol. 16(33)
Westlake University (CN), Institute for the Future (US)
National Natural Science Foundation of China
Affordable and clean energy
Openalex Percentile: Top 85%
Strong Light-Matter Interactions
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