Combined frequency comb and continuous wave cavity-enhanced optical-optical double-resonance spectrometer in the 1.7 µm range

We present an optical-optical double-resonance (OODR) spectrometer based on a 3.3 µm continuous wave pump and two cavity-enhanced probes: a frequency comb tunable in the 1.64-1.8 µm range, and a comb-referenced continuous wave (CW) laser tunable in the 1.6-1.75 µm range. The comb probe provides broad spectral coverage (bandwidth up to 7 THz) for simultaneous detection of many sub-Doppler OODR transitions with sub-MHz line position accuracy, while the CW probe allows targeting individual transitions with kHz accuracy and a higher signal-to-noise ratio in shorter time. Using the pump stabilized to the frequency of the R(0) transition in the <i>v</i>₃ band of methane and the comb probe covering the 5550 to 6070 cm^-1 interval, we detect 37 ladder-type transitions in the 3<i>v</i>₃ ← <i>v</i>₃ band region and 6 V-type transitions in the 2<i>v</i>₃ band region and assign them using available theoretical predictions. Using the CW probe, we measure selected ladder- and V-type transitions with much higher precision. We also detect Lamb dips in the R(0) - R(3) transitions of the 2<i>v</i>₃ band and report their center frequencies with kHz-level accuracy. The synergy effects of the comb- and CW-OODR open new possibilities in precision spectroscopy of levels that cannot be reached from the ground state.