Annulative endoperoxidation of tetronates
A novel, annulative endoperoxidation of tetronate derivatives bearing unsaturated side chains is presented. The reaction requires a simple setup and proceeds under mild conditions to generate tricyclic endoperoxides in modest diastereoselectivities and useful yields. A free-radical mechanism is proposed.
Authors
- Marat R. Talipov (ORCID: https://orcid.org/0000-0002-7559-9666)
- Rodolfo Tello‐Aburto (ORCID: https://orcid.org/0000-0001-8806-5762)
- Cory J. Windorff (ORCID: https://orcid.org/0000-0002-5208-9129)
- Najmeh Rahimi (ORCID: https://orcid.org/0000-0002-5893-5859)
- Bayler G. Barnes
- Saba Sehrish
- Samuel K. Akompong
Institutions
- New Mexico State University (US)
Publication Details
- Journal
- Organic & Biomolecular Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ob00663e
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- New Mexico State University
- National Institutes of Health
- National Institute of General Medical Sciences