Exploring the Thermal Degradation of Bakelite: Non-Isothermal Kinetic Modeling, Thermodynamic Insights, and Evolved Gas Analysis via Integrated In Situ TGA/MS and TGA/FT-IR Techniques

Thermogravimetric analysis (TGA) is a key technique for evaluating the kinetics and thermodynamics of thermal degradation, providing essential data for material assessment and system design. When coupled with Fourier-transform infrared (FT-IR) spectroscopy or mass spectroscopy (MS), it enables the identification of evolved gases and correlates mass loss with specific chemical species, offering detailed insight into decomposition mechanisms. In this study, TGA was coupled with FT-IR and MS to investigate the thermal degradation behavior of Bakelite, with the aim of evaluating its kinetic and thermodynamic parameters under non-isothermal conditions, identifying evolved volatile compounds, and elucidating the degradation process. The results showed that higher heating rates led to increased decomposition temperatures and broader dTG peaks due to thermal lag effects. The degradation proceeded in multiple stages between 220 °C and 860 °C, ultimately yielding a carbonaceous residue. The activation energy increased with conversion, particularly beyond 0.5, indicating a greater energy requirement as degradation progressed. Peak values at conversion degrees of 0.8-0.9 suggested enhanced thermal stability or changes in the dominant reaction mechanism. Detailed kinetic analysis revealed complex decomposition pathways with variable activation energies and a pronounced kinetic compensation effect. Thermodynamic analysis confirmed the endothermic nature of the process, with increasing energy demand and non-spontaneous degradation of the resulting char. TGA/FT-IR and TGA/MS analyses identified the release of several compounds, including CO₂, water, formaldehyde, and phenolic derivatives, at distinct stages. This comprehensive understanding of Bakelite's thermal behavior supports its optimization for high-temperature applications, enhances material reliability and safety, and contributes to sustainable processing and recycling strategies.