(C <sub>14</sub> H <sub>14</sub> N <sub>2</sub> )MCl <sub>4</sub> (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence
Two acentric (C 14 H 14 N 2 )MCl 4 (M = Zn, Cd) crystals were designed by combining planar π-conjugated (C 14 H 14 N 2 ) 2+ and [ZnCl 4 ] 2− /[CdCl 4 ] 2− groups. They show strong second-harmonic generation responses, large birefringence and broadband photoluminescence.
Authors
- Mingjun Xia (ORCID: https://orcid.org/0000-0003-2523-8296)
- Pifu Gong (ORCID: https://orcid.org/0000-0002-4656-1554)
- Xinhui Li (ORCID: https://orcid.org/0000-0003-2523-9002)
- Qi Miao (ORCID: https://orcid.org/0000-0003-2922-6663)
- Xinfang Wang (ORCID: https://orcid.org/0000-0003-2607-1360)
- Wenqiang Wang (ORCID: https://orcid.org/0000-0002-8194-3910)
- Zhen Jia (ORCID: https://orcid.org/0009-0006-4312-1277)
- Mingxing Chen (ORCID: https://orcid.org/0000-0001-9139-716X)
- Shujuan Zhuang
Institutions
- Shandong University of Technology (CN)
- Chinese Academy of Sciences (CN)
- Peking University (CN)
- Technical Institute of Physics and Chemistry (CN)
- Dezhou University (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi01234a
- Citations
- 8
- Primary Topic
- Nonlinear Optical Materials Research
- Type
- article
- Field-Weighted Citation Impact
- 3.42