Transformation of carbon dioxide catalyzed using an N-heterocyclic carbene copper(<scp>i</scp>)-embedded metal–organic framework
A Cu( i )-NHC motif was integrated into a 3D Zn-MOF utilizing an imidazolium ligand. The resulting Cu( i )-NHC@Zn-MOF exhibited high efficiency in catalyzing the carboxylation of terminal alkynes with carbon dioxide at atmospheric pressure.
Authors
- Gang Xiong (ORCID: https://orcid.org/0000-0002-2940-2949)
- Jie Guo (ORCID: https://orcid.org/0009-0005-2803-6464)
- Fu Ding (ORCID: https://orcid.org/0000-0001-5550-7974)
- Li-Xin You (ORCID: https://orcid.org/0000-0003-1017-3901)
- Xinyu Wang (ORCID: https://orcid.org/0000-0002-9167-2077)
- Ya‐Guang Sun (ORCID: https://orcid.org/0000-0001-5850-0938)
- Jinrong Li (ORCID: https://orcid.org/0000-0003-4755-1152)
Institutions
- Beijing Institute of Petrochemical Technology (CN)
- Lanzhou Petrochemical Polytechnic (CN)
- Shenyang University of Chemical Technology (CN)
Publication Details
- Journal
- CrystEngComm
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ce00627a
- Citations
- 2
- Primary Topic
- Carbon dioxide utilization in catalysis
- Type
- article
- Field-Weighted Citation Impact
- 1.41
Funders
- Shenyang University of Chemical Technology
- Department of Science and Technology of Liaoning Province