Impact of charge-density-wave pattern on the superconducting gap in Vanadium-based kagome superconductors

Kagome metals AV3Sb5 (A = K, Rb, Cs) provide a compelling platform to explore the interplay between superconductivity (SC) and charge-density-wave (CDW) orders. While distinct CDW orders have been identified in K/RbV3Sb5 versus CsV3Sb5, their influence on the SC order parameter remains unresolved. Here, we investigate low-energy quasiparticle excitations in AV3Sb5, uncovering a striking difference in SC gap anisotropy: K/RbV3Sb5 exhibit fully gapped, nearly isotropic s-wave states, in contrast to the strongly anisotropic SC gap in CsV3Sb5. Impurity scattering introduced via electron irradiation in K/RbV3Sb5 has a minimal impact on low-energy excitations, and it induces an increase in the SC transition temperature Tc, consistent with more isotropic s-wave SC competing with CDW order. Our theoretical analysis attributes the observed SC gap anisotropy differences to distinct CDW modulation patterns: the star-of-David structure unique to CsV3Sb5 preserves van Hove singularities near the Fermi level, promoting anisotropic s-wave SC with enhanced Tc via bond-order fluctuations. These findings establish a systematic framework for understanding the interplay between SC and CDW orders in AV3Sb5, driven by electron correlations. Kagome metal family, AV3Sb5(A = K, Rb, Cs), provide a platform to probe the interplay between superconductivity (SC) and charge density waves (CDW) and whether it is competitive or complementary. Here, the authors find a contrasting behavior that, while the superconductivity in A = Cs is susceptible to disorder, that in A = K, Rb is stabilized by disorder due to the competitive nature between the CDW and SC states. They attribute the results to the different CDW patterns in A = Cs and A = K, Rb, highlighting crucial role of CDW order to the SC order parameters in the kagome family.

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Publication Details

Journal
Communications Physics
Published
2025-07-18
DOI
https://doi.org/10.1038/s42005-025-02225-8
Primary Topic
Advanced Condensed Matter Physics
Type
article
Field-Weighted Citation Impact
0.00

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article

Impact of charge-density-wave pattern on the superconducting gap in Vanadium-based kagome superconductors

Andrea Capa Salinas, Hiroshi Kontani, Stephen D. Wilson, M. Roppongi et al.
Communications Physics
Advanced Condensed Matter Physics
article

Impact of charge-density-wave pattern on the superconducting gap in Vanadium-based kagome superconductors

Andrea Capa Salinas, Hiroshi Kontani, Stephen D. Wilson, M. Roppongi, M. Kończykowski, T. Shibauchi, K. Ishihara, Romain Grasset, Youichi Yamakawa, Rina Tazai, Brenden R. Ortiz, K. Imamura, K. Hashimoto, Fan Chen, T. Nagashima
article en

Abstract

Kagome metals AV3Sb5 (A = K, Rb, Cs) provide a compelling platform to explore the interplay between superconductivity (SC) and charge-density-wave (CDW) orders. While distinct CDW orders have been identified in K/RbV3Sb5 versus CsV3Sb5, their influence on the SC order parameter remains unresolved. Here, we investigate low-energy quasiparticle excitations in AV3Sb5, uncovering a striking difference in SC gap anisotropy: K/RbV3Sb5 exhibit fully gapped, nearly isotropic s-wave states, in contrast to the strongly anisotropic SC gap in CsV3Sb5. Impurity scattering introduced via electron irradiation in K/RbV3Sb5 has a minimal impact on low-energy excitations, and it induces an increase in the SC transition temperature Tc, consistent with more isotropic s-wave SC competing with CDW order. Our theoretical analysis attributes the observed SC gap anisotropy differences to distinct CDW modulation patterns: the star-of-David structure unique to CsV3Sb5 preserves van Hove singularities near the Fermi level, promoting anisotropic s-wave SC with enhanced Tc via bond-order fluctuations. These findings establish a systematic framework for understanding the interplay between SC and CDW orders in AV3Sb5, driven by electron correlations. Kagome metal family, AV3Sb5(A = K, Rb, Cs), provide a platform to probe the interplay between superconductivity (SC) and charge density waves (CDW) and whether it is competitive or complementary. Here, the authors find a contrasting behavior that, while the superconductivity in A = Cs is susceptible to disorder, that in A = K, Rb is stabilized by disorder due to the competitive nature between the CDW and SC states. They attribute the results to the different CDW patterns in A = Cs and A = K, Rb, highlighting crucial role of CDW order to the SC order parameters in the kagome family.

Communications PhysicsVol. 8(1)
Oak Ridge National Laboratory (US), Centre National de la Recherche Scientifique (FR), École Polytechnique (FR), University of California, Santa Barbara (US), Kyoto University (JP), Commissariat à l'Énergie Atomique et aux Énergies Alternatives (FR), Nagoya University (JP), The University of Tokyo (JP)
National Science Foundation, U.S. Department of Energy, Centre National de la Recherche Scientifique, Office of Science, University of California, Santa Barbara, Japan Society for the Promotion of Science, Division of Materials Research, Basic Energy Sciences
Openalex Percentile: Top 88%
Advanced Condensed Matter Physics
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