Impact of charge-density-wave pattern on the superconducting gap in Vanadium-based kagome superconductors
Kagome metals AV3Sb5 (A = K, Rb, Cs) provide a compelling platform to explore the interplay between superconductivity (SC) and charge-density-wave (CDW) orders. While distinct CDW orders have been identified in K/RbV3Sb5 versus CsV3Sb5, their influence on the SC order parameter remains unresolved. Here, we investigate low-energy quasiparticle excitations in AV3Sb5, uncovering a striking difference in SC gap anisotropy: K/RbV3Sb5 exhibit fully gapped, nearly isotropic s-wave states, in contrast to the strongly anisotropic SC gap in CsV3Sb5. Impurity scattering introduced via electron irradiation in K/RbV3Sb5 has a minimal impact on low-energy excitations, and it induces an increase in the SC transition temperature Tc, consistent with more isotropic s-wave SC competing with CDW order. Our theoretical analysis attributes the observed SC gap anisotropy differences to distinct CDW modulation patterns: the star-of-David structure unique to CsV3Sb5 preserves van Hove singularities near the Fermi level, promoting anisotropic s-wave SC with enhanced Tc via bond-order fluctuations. These findings establish a systematic framework for understanding the interplay between SC and CDW orders in AV3Sb5, driven by electron correlations. Kagome metal family, AV3Sb5(A = K, Rb, Cs), provide a platform to probe the interplay between superconductivity (SC) and charge density waves (CDW) and whether it is competitive or complementary. Here, the authors find a contrasting behavior that, while the superconductivity in A = Cs is susceptible to disorder, that in A = K, Rb is stabilized by disorder due to the competitive nature between the CDW and SC states. They attribute the results to the different CDW patterns in A = Cs and A = K, Rb, highlighting crucial role of CDW order to the SC order parameters in the kagome family.
Authors
- Andrea Capa Salinas (ORCID: https://orcid.org/0000-0002-5308-7520)
- Hiroshi Kontani (ORCID: https://orcid.org/0000-0002-8127-7903)
- Stephen D. Wilson (ORCID: https://orcid.org/0000-0003-3733-930X)
- M. Roppongi (ORCID: https://orcid.org/0000-0002-6036-8873)
- M. Kończykowski (ORCID: https://orcid.org/0000-0003-3376-5635)
- T. Shibauchi (ORCID: https://orcid.org/0000-0001-5831-4924)
- K. Ishihara (ORCID: https://orcid.org/0000-0002-8835-342X)
- Romain Grasset (ORCID: https://orcid.org/0000-0003-4769-8947)
- Youichi Yamakawa (ORCID: https://orcid.org/0000-0002-6456-381X)
- Rina Tazai (ORCID: https://orcid.org/0000-0001-9794-3600)
- Brenden R. Ortiz (ORCID: https://orcid.org/0000-0002-1333-7003)
- K. Imamura (ORCID: https://orcid.org/0000-0001-7112-7701)
- K. Hashimoto (ORCID: https://orcid.org/0000-0003-4651-4077)
- Fan Chen (ORCID: https://orcid.org/0000-0003-4482-3116)
- T. Nagashima (ORCID: https://orcid.org/0009-0007-9305-9317)
Institutions
- Oak Ridge National Laboratory (US)
- Centre National de la Recherche Scientifique (FR)
- École Polytechnique (FR)
- University of California, Santa Barbara (US)
- Kyoto University (JP)
- Commissariat à l'Énergie Atomique et aux Énergies Alternatives (FR)
- Nagoya University (JP)
- The University of Tokyo (JP)
Publication Details
- Journal
- Communications Physics
- Published
- 2025-07-18
- DOI
- https://doi.org/10.1038/s42005-025-02225-8
- Primary Topic
- Advanced Condensed Matter Physics
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Science Foundation
- U.S. Department of Energy
- Centre National de la Recherche Scientifique
- Office of Science
- University of California, Santa Barbara
- Japan Society for the Promotion of Science
- Division of Materials Research
- Basic Energy Sciences