Nanoscale AC Electroosmotic Flow and the Frequency–Size Scaling Observed beyond the Charge Relaxation Regime

We present the first observation of AC electroosmosis (ACEO) flow at nanoscale structures in the MHz range, offering new insights into electrokinetic phenomena in this frequency regime. Our findings reveal that ACEO occurs at frequencies much higher than previously anticipated, even surpassing the Debye-Hückel frequency associated with charge relaxation. Despite remaining undetected for over two decades, this result is corroborated by the frequency-size scaling laws derived in this work from the existing ACEO theory. We contextualize these findings within the historical development of electrokinetic phenomena and discuss their implications for the current theoretical framework of ACEO.

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Publication Details

Journal
Nano Letters
Published
2025-08-08
DOI
https://doi.org/10.1021/acs.nanolett.5c00057
Citations
1
Primary Topic
Microfluidic and Bio-sensing Technologies
Type
article
Field-Weighted Citation Impact
0.67

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article

Nanoscale AC Electroosmotic Flow and the Frequency–Size Scaling Observed beyond the Charge Relaxation Regime

Leonardo Lesser‐Rojas, Chia‐Fu Chou, Gerhard Heinrich Blankenburg, Huberth Hernández-Alpízar
1 citations
Nano Letters
Microfluidic and Bio-sensing Technologies
0.67
article

Nanoscale AC Electroosmotic Flow and the Frequency–Size Scaling Observed beyond the Charge Relaxation Regime

Leonardo Lesser‐Rojas, Chia‐Fu Chou, Gerhard Heinrich Blankenburg, Huberth Hernández-Alpízar
article en
1 citations

Abstract

We present the first observation of AC electroosmosis (ACEO) flow at nanoscale structures in the MHz range, offering new insights into electrokinetic phenomena in this frequency regime. Our findings reveal that ACEO occurs at frequencies much higher than previously anticipated, even surpassing the Debye-Hückel frequency associated with charge relaxation. Despite remaining undetected for over two decades, this result is corroborated by the frequency-size scaling laws derived in this work from the existing ACEO theory. We contextualize these findings within the historical development of electrokinetic phenomena and discuss their implications for the current theoretical framework of ACEO.

Nano LettersVol. 25(35)
National Taiwan University (TW), Center for NanoScience (DE), Universidad de Costa Rica (CR), Research Center for Applied Science, Academia Sinica (TW), Institute of Physics, Academia Sinica (TW), Institute of Atomic and Molecular Sciences, Academia Sinica (TW), Institute of Chemistry, Academia Sinica (TW), Academia Sinica (TW)
Asian Office of Aerospace Research and Development, Academia Sinica, National Science and Technology Council, Air Force Office of Scientific Research, European Office of Aerospace Research and Development
Openalex Percentile: Top 28%
Microfluidic and Bio-sensing Technologies
0.67
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