Electrochemically Driven Strategies Enabling the Construction of Carbon–Carbon/Carbon–Heteroatom Bonds

Abstract The scientific community has recently shown a significant interest in electro-organic synthesis, which has been recognized as a promising, environmentally friendly, and sustainable tool for organic synthesis. Here, the electric current acts as a reagent to drive chemical transformations, which avoids the usage of hazardous, oxidizing, and reducing reagents. Therefore, herein, we present an account of recent developments in electrochemical synthetic methodologies that were developed in our laboratory, such as the synthesis of tertiary alcohols, 3-selenylindoles, sulfenyl-phenanthrenes, spiro-cyclohexadienone indenes, β-hydroxy-selenides, 4-sulfenyl-isochromenones, and para-hydroxysulfonamides/acetanilides. We hope this account will provide the feasibility for and further advancements in reaction design, mechanistic understanding, and the pertinence of electro-catalysis in academic and industry frameworks.

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Publication Details

Journal
Synlett
Published
2025-08-04
DOI
https://doi.org/10.1055/a-2675-4286
Primary Topic
Radical Photochemical Reactions
Type
article
Field-Weighted Citation Impact
0.00
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article

Electrochemically Driven Strategies Enabling the Construction of Carbon–Carbon/Carbon–Heteroatom Bonds

Gedu Satyanarayana, Anil Balajirao Dapkekar
Synlett
Radical Photochemical Reactions
article

Electrochemically Driven Strategies Enabling the Construction of Carbon–Carbon/Carbon–Heteroatom Bonds

Gedu Satyanarayana, Anil Balajirao Dapkekar
article en

Abstract

Abstract The scientific community has recently shown a significant interest in electro-organic synthesis, which has been recognized as a promising, environmentally friendly, and sustainable tool for organic synthesis. Here, the electric current acts as a reagent to drive chemical transformations, which avoids the usage of hazardous, oxidizing, and reducing reagents. Therefore, herein, we present an account of recent developments in electrochemical synthetic methodologies that were developed in our laboratory, such as the synthesis of tertiary alcohols, 3-selenylindoles, sulfenyl-phenanthrenes, spiro-cyclohexadienone indenes, β-hydroxy-selenides, 4-sulfenyl-isochromenones, and para-hydroxysulfonamides/acetanilides. We hope this account will provide the feasibility for and further advancements in reaction design, mechanistic understanding, and the pertinence of electro-catalysis in academic and industry frameworks.

SynlettVol. 36(20)
Indian Institute of Technology Hyderabad (IN)
Responsible consumption and production
Openalex Percentile: Top 85%
Radical Photochemical Reactions
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