Synergistic cross-coupling catalysis: a trialkylphosphine/Pd catalyst tethered to MOF-808(Hf) is very effective for Suzuki–Miyaura coupling of problematic nucleophiles
MOF-808(Hf) with grafted trialkylphosphines loaded with Pd catalyses Suzuki–Miyaura coupling of functionalised aryl boronic acids with aryl chlorides and demanding cross-couplings of electron-deficient nucleophiles.
Authors
- Irene Giménez‐Nueno (ORCID: https://orcid.org/0000-0001-7004-7099)
- Matthew L. Clarke (ORCID: https://orcid.org/0000-0002-2444-1244)
- Aaron B. Naden (ORCID: https://orcid.org/0000-0003-2876-6991)
- Charlotte A. Lane
- Paul A. Wright (ORCID: https://orcid.org/0000-0002-4243-9957)
- Federico Grillo (ORCID: https://orcid.org/0000-0001-9961-1212)
- Soneni Ndlovu (ORCID: https://orcid.org/0000-0002-5479-1624)
Institutions
- University of St Andrews (GB)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d4cy01178c
- Primary Topic
- Catalytic Cross-Coupling Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- GlaxoSmithKline
- Engineering and Physical Sciences Research Council