Adsorption of Neonol AF 9-9 on the surface of intercalated and thermally expanded graphite

A comparative study of the sorption properties of intercalated and thermally expanded graphite with re-spect to the nonionic surfactant neonol AF 9-9, which is an oxyethylatedmonoalkyl phenol, was carried out using the tensiometer method. It was experimentally established that the adsorption process on both materials is described by the Freundlich isotherm. This indicates the physical nature of sorption and the energy heterogeneity of the surface of inter-calated and thermally expanded graphite. Since heat treatment leads to a significant change in the structure of the mate-rial ‒ the formation of a developed system of micropores and an increase in the specific surface ‒ thermally expanded graphite demonstrates a 4-fold greater adsorption capacity compared to the intercalated form. The results obtained are of great importance for the development of effective sorption methods for cleaning industrial wastewater from toxic surfactants.Keywords:

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Publication Details

Journal
Вестник Пермского университета Серия «Химия» = Bulletin of Perm University CHEMISTRY
Published
2025-01-01
DOI
https://doi.org/10.17072/2223-1838-2025-2-100-107
Primary Topic
Graphene research and applications
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article
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article

Adsorption of Neonol AF 9-9 on the surface of intercalated and thermally expanded graphite

М. Г. Щербань, Maria A. Chertkova
Вестник Пермского университета Серия «Химия» = Bulletin of Perm University CHEMISTRY
Graphene research and applications
article

Adsorption of Neonol AF 9-9 on the surface of intercalated and thermally expanded graphite

М. Г. Щербань, Maria A. Chertkova
article en

Abstract

A comparative study of the sorption properties of intercalated and thermally expanded graphite with re-spect to the nonionic surfactant neonol AF 9-9, which is an oxyethylatedmonoalkyl phenol, was carried out using the tensiometer method. It was experimentally established that the adsorption process on both materials is described by the Freundlich isotherm. This indicates the physical nature of sorption and the energy heterogeneity of the surface of inter-calated and thermally expanded graphite. Since heat treatment leads to a significant change in the structure of the mate-rial ‒ the formation of a developed system of micropores and an increase in the specific surface ‒ thermally expanded graphite demonstrates a 4-fold greater adsorption capacity compared to the intercalated form. The results obtained are of great importance for the development of effective sorption methods for cleaning industrial wastewater from toxic surfactants.Keywords:

Вестник Пермского университета Серия «Химия» = Bulletin of Perm University CHEMISTRYVol. 15(2)
Openalex Percentile: Top 85%
Graphene research and applications
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