Synthesis of a Palladium(II) Complex of N-(2,7-Dimethyloctadienyl)benzimidazole

Based on N-(2,7-dimethyloctadienyl)benzimidazole (1), a benzimidazolyl terpene of irregular structure, a palladium(II) complex was obtained in order to study its structure and suitability for biological evaluation. It was found that the volume of ligand 1 is large enough to form a stable trans-complex. According to the results of X-ray diffraction analysis, only [1-(2,7-dimethyl-2,7-octadien-1-yl)benzimidazole]palladium(II) dichloride (2) of trans-configuration is formed.

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Publication Details

Journal
INEOS OPEN
Published
2025-04-29
DOI
https://doi.org/10.32931/io2529a
Primary Topic
Synthesis and Reactions of Organic Compounds
Type
article
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article

Synthesis of a Palladium(II) Complex of N-(2,7-Dimethyloctadienyl)benzimidazole

E. A. Petrushkina, Elena G. Kononova, Т. В. Стрелкова, F.M. Dolgushin
INEOS OPEN
Synthesis and Reactions of Organic Compounds
article

Synthesis of a Palladium(II) Complex of N-(2,7-Dimethyloctadienyl)benzimidazole

E. A. Petrushkina, Elena G. Kononova, Т. В. Стрелкова, F.M. Dolgushin
article en

Abstract

Based on N-(2,7-dimethyloctadienyl)benzimidazole (1), a benzimidazolyl terpene of irregular structure, a palladium(II) complex was obtained in order to study its structure and suitability for biological evaluation. It was found that the volume of ligand 1 is large enough to form a stable trans-complex. According to the results of X-ray diffraction analysis, only [1-(2,7-dimethyl-2,7-octadien-1-yl)benzimidazole]palladium(II) dichloride (2) of trans-configuration is formed.

INEOS OPENVol. 8(1-3)
Openalex Percentile: Top 85%
Synthesis and Reactions of Organic Compounds
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