Organic semiconductor frameworks integrating bay-substituted perylene bisimides as screw dislocation units in onion-like π–π stacked architectures
Core-twisted PBI-based COFs grown on WO 3 3D-NS photoanodes enable photocurrent densities up to 590 ± 50 μA cm −2 under green-light irradiation (>20 h, 1 sun, λ > 490 nm) using sulfonate hydroquinone as a redox mediator.
Authors
- Thomas Gobbato (ORCID: https://orcid.org/0000-0002-8171-2717)
- Marcella Bonchio (ORCID: https://orcid.org/0000-0002-7445-0296)
- Daniele Rosa‐Gastaldo (ORCID: https://orcid.org/0000-0002-6396-6035)
- Francesco Rigodanza (ORCID: https://orcid.org/0000-0002-1097-3282)
- Silvia Bracco (ORCID: https://orcid.org/0000-0002-2575-6424)
- Silvia Bordiga
- Gloria Berlier (ORCID: https://orcid.org/0000-0001-7720-3584)
- Angiolina Comotti (ORCID: https://orcid.org/0000-0002-8396-8951)
- Leonardo Cognigni (ORCID: https://orcid.org/0009-0005-4245-3045)
- Jintao Liu (ORCID: https://orcid.org/0000-0003-1203-3187)
- Stefano Magliocco
Institutions
- University of Padua (IT)
- National Interuniversity Consortium of Materials Science and Technology (IT)
- Institute on Membrane Technology (IT)
- University of Turin (IT)
- University of Milano-Bicocca (IT)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta05253j
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Dipartimenti di Eccellenza
- European Commission
- Ministero dell’Istruzione, dell’Università e della Ricerca
- Università degli Studi di Padova
- Ministero dell'Università e della Ricerca
- HORIZON EUROPE European Innovation Council