Investigation Into the Mechanistic Insights and Performance Evaluation of Advanced Viscosity Reducing Agents for Heavy Oil Invaded Oil‐Based Drilling Fluids via Asphaltene Structure Disruption

ABSTRACT To tackle the viscosity surge in oil‐based drilling fluids (OBDFs) due to heavy oil invasion, a novel tetrapolymer viscosity reducer (PVR) was synthesized from diisobutylene, isobutylene, isoprene, and maleic anhydride. FT‐IR, NMR, and TGA confirmed its structure and high thermal stability (decomposition at 398°C). Tests showed PVR reduced plastic viscosity of contaminated fluids by 21 mPa s and yield point by over 12.5 Pa, achieved by disrupting asphaltene π‐π stacking and hydrogen bonds, reducing aggregate size ( D 50 from 31.345 to 6.265 μm). At 2% dosage, it maintained emulsion stability (breakdown voltage 486 V, above 400 V threshold). After 72‐h 180°C aging, PVR performed better: plastic viscosity showed little change (72–71 mPa s), yield point dropped sharply (16–7 Pa), and density difference was 0.01 g/cm 3 (vs. 0.04 g/cm 3 for blank), indicating superior high‐temperature long‐term stability. This offers a reliable solution for optimizing deep‐well high‐temperature drilling fluids.

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Publication Details

Journal
Journal of Applied Polymer Science
Published
2025-08-04
DOI
https://doi.org/10.1002/app.57790
Citations
1
Primary Topic
Petroleum Processing and Analysis
Type
article
Field-Weighted Citation Impact
0.75
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article

Investigation Into the Mechanistic Insights and Performance Evaluation of Advanced Viscosity Reducing Agents for Heavy Oil Invaded Oil‐Based Drilling Fluids via Asphaltene Structure Disruption

Han Zhao, Gong‐Rang Li, Ye‐Cheng Li, Wei Liu et al.
1 citations
Journal of Applied Polymer Science
Petroleum Processing and Analysis
0.75
article

Investigation Into the Mechanistic Insights and Performance Evaluation of Advanced Viscosity Reducing Agents for Heavy Oil Invaded Oil‐Based Drilling Fluids via Asphaltene Structure Disruption

Han Zhao, Gong‐Rang Li, Ye‐Cheng Li, Wei Liu, Qiang Lan, Huang Wei, Chengjun Wang
article en
1 citations

Abstract

ABSTRACT To tackle the viscosity surge in oil‐based drilling fluids (OBDFs) due to heavy oil invasion, a novel tetrapolymer viscosity reducer (PVR) was synthesized from diisobutylene, isobutylene, isoprene, and maleic anhydride. FT‐IR, NMR, and TGA confirmed its structure and high thermal stability (decomposition at 398°C). Tests showed PVR reduced plastic viscosity of contaminated fluids by 21 mPa s and yield point by over 12.5 Pa, achieved by disrupting asphaltene π‐π stacking and hydrogen bonds, reducing aggregate size ( D 50 from 31.345 to 6.265 μm). At 2% dosage, it maintained emulsion stability (breakdown voltage 486 V, above 400 V threshold). After 72‐h 180°C aging, PVR performed better: plastic viscosity showed little change (72–71 mPa s), yield point dropped sharply (16–7 Pa), and density difference was 0.01 g/cm 3 (vs. 0.04 g/cm 3 for blank), indicating superior high‐temperature long‐term stability. This offers a reliable solution for optimizing deep‐well high‐temperature drilling fluids.

Journal of Applied Polymer ScienceVol. 142(46)
Shengli Oilfield Central Hospital (CN), Petroleum Technology Company (Norway) (NO), China University of Petroleum, East China (CN)
Openalex Percentile: Top 28%
Petroleum Processing and Analysis
0.75
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Investigation Into the Mechanistic Insights and Performance Evaluation of Advanced Viscosity Reducing Agents for Heavy Oil Invaded Oil‐Based Drilling Fluids via Asphaltene Structure Disruption — Han Zhao, Gong‐Rang Li, et al. · Journal of Applied Polymer Science (2025) | TGRS Research Map | TGRS