Breakdown Characteristics of C<sub>4</sub>F<sub>7</sub>N/CO<sub>2</sub>/O<sub>2</sub> Gas Mixtures with Low Content of C<sub>4</sub>F<sub>7</sub>N

Perfluoroisobutyronitrile (C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N) gas mixture is a promising SF<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</inf> alternative characterized by its low global warming potential (GWP), high insulation strength, and short atmospheric lifetime. Considering the persistent environmental pollution and bioaccumulation risks associated with per- and polyfluoroalkyl substances (PFAS), regulatory measures have been implemented across regions to control PFAS and F-gases. Therefore, investigating the insulating performance of C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N gas mixtures with low concentration is essential. In this study, the influence of oxygen content and gas pressure on the insulation performance of C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N/CO<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf>/O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> gas mixtures with low content of C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N were investigated. The results show that, compared with C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N mixture without O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf>, increasing oxygen content at 0.1 MPa reduced the insulating strength of the gas mixture, with the smallest reduction of 0.33% observed at an O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> concent of 4%. At 0.2 MPa, adding 4%–8% oxygen decreased the insulation strength, while an O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> content of 12% enhances it by 7.36%. At pressures between 0.3 and 0.4 MPa, higher oxygen concentrations were found to enhance the insulation performance., with the maximum increases of 9.35% and 8.20% occurring at 8% O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf>(0.3 MPa) and 12% O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf>(0.4 MPa), respectively.

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Published
2025-05-23
DOI
https://doi.org/10.1109/ieecsc64206.2025.11099686
Primary Topic
High voltage insulation and dielectric phenomena
Type
article
Field-Weighted Citation Impact
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article

Breakdown Characteristics of C4F7N/CO2/O2 Gas Mixtures with Low Content of C4F7N

Tianxin Zhuang, X. L. Lu, Jing Yan, Pu Chen et al.
4 links
High voltage insulation and dielectric phenomena
article

Breakdown Characteristics of C4F7N/CO2/O2 Gas Mixtures with Low Content of C4F7N

Tianxin Zhuang, X. L. Lu, Jing Yan, Pu Chen, Yuxin Lin, Hanyan Xiao
article en

Abstract

Perfluoroisobutyronitrile (C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N) gas mixture is a promising SF<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</inf> alternative characterized by its low global warming potential (GWP), high insulation strength, and short atmospheric lifetime. Considering the persistent environmental pollution and bioaccumulation risks associated with per- and polyfluoroalkyl substances (PFAS), regulatory measures have been implemented across regions to control PFAS and F-gases. Therefore, investigating the insulating performance of C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N gas mixtures with low concentration is essential. In this study, the influence of oxygen content and gas pressure on the insulation performance of C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N/CO<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf>/O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> gas mixtures with low content of C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N were investigated. The results show that, compared with C<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</inf>F<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</inf>N mixture without O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf>, increasing oxygen content at 0.1 MPa reduced the insulating strength of the gas mixture, with the smallest reduction of 0.33% observed at an O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> concent of 4%. At 0.2 MPa, adding 4%–8% oxygen decreased the insulation strength, while an O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> content of 12% enhances it by 7.36%. At pressures between 0.3 and 0.4 MPa, higher oxygen concentrations were found to enhance the insulation performance., with the maximum increases of 9.35% and 8.20% occurring at 8% O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf>(0.3 MPa) and 12% O<inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf>(0.4 MPa), respectively.

Electric Power Research Institute (US), Shanghai Electric (China) (CN), State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University (CN)
National Key Research and Development Program of China
Openalex Percentile: Top 86%
High voltage insulation and dielectric phenomena
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