Tuning flexibility in metal–organic frameworks <i>via</i> linker per-fluorination: revisiting the adsorption-induced breathing of MIL-53(Al)
In situ characterisation of the multi-step adsorption-induced breathing behaviour of F 4 -MIL-53(Al) unveiled the impact of fluorination on framework flexibility and adsorption properties, offering new insights into dynamic porosity in MOFs.
Authors
- Valentina Crocellà (ORCID: https://orcid.org/0000-0002-3606-8424)
- Ferdinando Costantino (ORCID: https://orcid.org/0000-0002-2120-1456)
- Maria Sole Notari
- Matteo Signorile (ORCID: https://orcid.org/0000-0003-0521-3702)
- Virginia Guiotto (ORCID: https://orcid.org/0009-0000-2067-8933)
- Francesca Nardelli (ORCID: https://orcid.org/0000-0002-9793-1367)
- Susana García (ORCID: https://orcid.org/0000-0002-3713-311X)
- Jacopo Perego (ORCID: https://orcid.org/0000-0003-4795-2060)
- Silvia Bordiga
- Alberto Ricchebuono (ORCID: https://orcid.org/0000-0003-0497-3785)
- Angiolina Comotti (ORCID: https://orcid.org/0000-0002-8396-8951)
- Marco Taddei (ORCID: https://orcid.org/0000-0003-2805-6375)
- Diletta Morelli Venturi (ORCID: https://orcid.org/0000-0001-6978-5609)
- Lucia Calucci (ORCID: https://orcid.org/0000-0002-3080-8807)
Institutions
- University of Pisa (IT)
- IFP Énergies nouvelles (FR)
- University of Perugia (IT)
- Christian-Albrechts-Universität zu Kiel (DE)
- Heriot-Watt University (GB)
- Institute for the Chemistry of OrganoMetallic Compounds (IT)
- University of Turin (IT)
- University of Milano-Bicocca (IT)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta04373e
- Citations
- 3
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.61
Funders
- Dipartimenti di Eccellenza
- European Commission
- Deutsche Forschungsgemeinschaft
- HORIZON EUROPE Framework Programme