Flow electrochemical oxidation of <i>N</i>-nitrosamines to <i>N</i>-nitramines

<i>N</i>-Nitro groups are a key functionality found in most energetic compounds. Conventional synthetic routes require the use of harsh reagents, such as fuming nitric acid. As an alternative, a biphasic electrochemical flow synthesis of <i>N</i>-nitramines from the oxidation of <i>N</i>-nitrosamines using molecular oxygen has been developed, proceeding <i>via</i> paired electrolysis.