Access to benzo[ <i>e</i> ][1,3]thiazin-4-ones <i>via</i> PCy <sub>3</sub> -mediated annulations of benzo[ <i>c</i> ][1,2]dithiol-3-ones with iso(thio)cyanates

A novel organophosphine-mediated annulation reaction of benzo[ c ][1,2]dithiol-3-ones with iso(thio)cyanates to synthesise benzo[ e ][1,3]thiazin-4-one derivatives has been developed, which proceeds via an S atom to C–N unit exchange strategy.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo01013f
Citations
4
Primary Topic
Synthesis of heterocyclic compounds
Type
article
Field-Weighted Citation Impact
3.74
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article

Access to benzo[ e ][1,3]thiazin-4-ones via PCy 3 -mediated annulations of benzo[ c ][1,2]dithiol-3-ones with iso(thio)cyanates

Chuanjun Song, Mao-Mei Zhu, Jie Ren, Yangang Wu et al.
4 citations
Organic Chemistry Frontiers
Synthesis of heterocyclic compounds
3.74
article

Access to benzo[ e ][1,3]thiazin-4-ones via PCy 3 -mediated annulations of benzo[ c ][1,2]dithiol-3-ones with iso(thio)cyanates

Chuanjun Song, Mao-Mei Zhu, Jie Ren, Yangang Wu, Chengxiang Yi, Weimin Zhu
article en
4 citations

Abstract

A novel organophosphine-mediated annulation reaction of benzo[ c ][1,2]dithiol-3-ones with iso(thio)cyanates to synthesise benzo[ e ][1,3]thiazin-4-one derivatives has been developed, which proceeds via an S atom to C–N unit exchange strategy.

Organic Chemistry FrontiersVol. 12(22)
Zhengzhou University of Light Industry (CN), Zhengzhou University (CN), Zhengzhou University of Science and Technology (CN), Henan University of Engineering (CN)
Openalex Percentile: Top 7%
Synthesis of heterocyclic compounds
3.74
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Access to benzo[ <i>e</i> ][1,3]thiazin-4-ones <i>via</i> PCy <sub>3</sub> -mediated annulations of benzo[ <i>c</i> ][1,2]dithiol-3-ones with iso(thio)cyanates — Chuanjun Song, Mao-Mei Zhu, et al. · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS