Sub-solidus evolution of plagioclase-hosted Fe-Ti oxide micro-inclusions from oceanic gabbros, Mid-Atlantic ridge (10–13°N)
Iron‑titanium oxide minerals are highly reactive under changing P-T-f O 2 conditions, and their chemical compositions and phase relations are important petrogenetic indicators. In this study, we use optical-, scanning electron-, and scanning transmission electron microscopy to investigate the sub-solidus and hydrothermal evolution of plagioclase-hosted Fe Ti oxide micro-inclusions from two types of oceanic gabbro dredged from the Mid-Atlantic Ridge at 10–13°N and exhibiting different types of hydrothermal alterations. Initially, the micro-inclusions formed as oriented, needle-shaped titanomagnetite, by precipitation from Fe- and Ti-bearing plagioclase. In most of the studied gabbros, such inclusions evolved into magnetite-ilmenite intergrowths by high-temperature oxidation above the Curie temperature of magnetite. Further evolution of the Fe Ti oxide micro-inclusions occurred during hydrothermal alteration at temperatures below the Curie temperature. Under low-intensity hydrothermal alteration, the micro-inclusions underwent minor dissolution and recrystallization. In contrast, intensive hydrothermal alteration under relatively reducing conditions resulted in substantial recrystallization and formation of magnetite-ulvospinel micro-inclusions, which were subsequently transformed into fine-grained magnetite-ilmenite ± ulvospinel aggregates. The phase contents and the microstructures of the plagioclase-hosted Fe Ti oxide micro-inclusions, formed during the sub-solidus and hydrothermal evolution, provide insights into their evolution during cooling under changing redox conditions. These features are crucial for interpreting paleomagnetic measurements of Fe-rich gabbros, which often feature plagioclase hosting Fe Ti oxide micro-inclusions. • Hydrothermal events alter the configurations of hosted Fe Ti oxide micro-inclusions. • Intensity of the events can recrystallize micro-inclusions leading to two generations. • Stage of the events affect chemistry, oxidation, exsolution states of the inclusions. • The transformations of the micro-inclusions are examined across various scales. • Evolutions of the inclusions bias paleomagnetic signals carried by these inclusions.
Authors
- Rainer Abart (ORCID: https://orcid.org/0000-0001-9562-450X)
- Ge Bian (ORCID: https://orcid.org/0000-0001-7376-4720)
- О. М. Zhilicheva
- A. N. Pertsev (ORCID: https://orcid.org/0000-0002-8126-6251)
- Qianqian Lan (ORCID: https://orcid.org/0000-0002-9215-4925)
- András Kovács (ORCID: https://orcid.org/0000-0001-8485-991X)
- Olga Ageeva (ORCID: https://orcid.org/0000-0002-0158-2749)
- Rafal E. Dunin–Borkowski (ORCID: https://orcid.org/0000-0001-8082-0647)
- Gerlinde Habler (ORCID: https://orcid.org/0000-0001-6405-230X)
Institutions
- University of Vienna (AT)
- Ernst Ruska Centre (DE)
- Institute of Geology of Ore Deposits Petrography Mineralogy and Geochemistry (RU)
Publication Details
- Journal
- Lithos
- Published
- 2025-08-04
- DOI
- https://doi.org/10.1016/j.lithos.2025.108211
- Primary Topic
- Geomagnetism and Paleomagnetism Studies
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Russian Foundation for Basic Research
- Austrian Science Fund
- Horizon 2020 Framework Programme
- HORIZON EUROPE Framework Programme