Sub-solidus evolution of plagioclase-hosted Fe-Ti oxide micro-inclusions from oceanic gabbros, Mid-Atlantic ridge (10–13°N)

Iron‑titanium oxide minerals are highly reactive under changing P-T-f O 2 conditions, and their chemical compositions and phase relations are important petrogenetic indicators. In this study, we use optical-, scanning electron-, and scanning transmission electron microscopy to investigate the sub-solidus and hydrothermal evolution of plagioclase-hosted Fe Ti oxide micro-inclusions from two types of oceanic gabbro dredged from the Mid-Atlantic Ridge at 10–13°N and exhibiting different types of hydrothermal alterations. Initially, the micro-inclusions formed as oriented, needle-shaped titanomagnetite, by precipitation from Fe- and Ti-bearing plagioclase. In most of the studied gabbros, such inclusions evolved into magnetite-ilmenite intergrowths by high-temperature oxidation above the Curie temperature of magnetite. Further evolution of the Fe Ti oxide micro-inclusions occurred during hydrothermal alteration at temperatures below the Curie temperature. Under low-intensity hydrothermal alteration, the micro-inclusions underwent minor dissolution and recrystallization. In contrast, intensive hydrothermal alteration under relatively reducing conditions resulted in substantial recrystallization and formation of magnetite-ulvospinel micro-inclusions, which were subsequently transformed into fine-grained magnetite-ilmenite ± ulvospinel aggregates. The phase contents and the microstructures of the plagioclase-hosted Fe Ti oxide micro-inclusions, formed during the sub-solidus and hydrothermal evolution, provide insights into their evolution during cooling under changing redox conditions. These features are crucial for interpreting paleomagnetic measurements of Fe-rich gabbros, which often feature plagioclase hosting Fe Ti oxide micro-inclusions. • Hydrothermal events alter the configurations of hosted Fe Ti oxide micro-inclusions. • Intensity of the events can recrystallize micro-inclusions leading to two generations. • Stage of the events affect chemistry, oxidation, exsolution states of the inclusions. • The transformations of the micro-inclusions are examined across various scales. • Evolutions of the inclusions bias paleomagnetic signals carried by these inclusions.

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Publication Details

Journal
Lithos
Published
2025-08-04
DOI
https://doi.org/10.1016/j.lithos.2025.108211
Primary Topic
Geomagnetism and Paleomagnetism Studies
Type
article
Field-Weighted Citation Impact
0.00

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article

Sub-solidus evolution of plagioclase-hosted Fe-Ti oxide micro-inclusions from oceanic gabbros, Mid-Atlantic ridge (10–13°N)

Rainer Abart, Ge Bian, О. М. Zhilicheva, A. N. Pertsev et al.
Lithos
Geomagnetism and Paleomagnetism Studies
article

Sub-solidus evolution of plagioclase-hosted Fe-Ti oxide micro-inclusions from oceanic gabbros, Mid-Atlantic ridge (10–13°N)

Rainer Abart, Ge Bian, О. М. Zhilicheva, A. N. Pertsev, Qianqian Lan, András Kovács, Olga Ageeva, Rafal E. Dunin–Borkowski, Gerlinde Habler
article en

Abstract

Iron‑titanium oxide minerals are highly reactive under changing P-T-f O 2 conditions, and their chemical compositions and phase relations are important petrogenetic indicators. In this study, we use optical-, scanning electron-, and scanning transmission electron microscopy to investigate the sub-solidus and hydrothermal evolution of plagioclase-hosted Fe Ti oxide micro-inclusions from two types of oceanic gabbro dredged from the Mid-Atlantic Ridge at 10–13°N and exhibiting different types of hydrothermal alterations. Initially, the micro-inclusions formed as oriented, needle-shaped titanomagnetite, by precipitation from Fe- and Ti-bearing plagioclase. In most of the studied gabbros, such inclusions evolved into magnetite-ilmenite intergrowths by high-temperature oxidation above the Curie temperature of magnetite. Further evolution of the Fe Ti oxide micro-inclusions occurred during hydrothermal alteration at temperatures below the Curie temperature. Under low-intensity hydrothermal alteration, the micro-inclusions underwent minor dissolution and recrystallization. In contrast, intensive hydrothermal alteration under relatively reducing conditions resulted in substantial recrystallization and formation of magnetite-ulvospinel micro-inclusions, which were subsequently transformed into fine-grained magnetite-ilmenite ± ulvospinel aggregates. The phase contents and the microstructures of the plagioclase-hosted Fe Ti oxide micro-inclusions, formed during the sub-solidus and hydrothermal evolution, provide insights into their evolution during cooling under changing redox conditions. These features are crucial for interpreting paleomagnetic measurements of Fe-rich gabbros, which often feature plagioclase hosting Fe Ti oxide micro-inclusions. • Hydrothermal events alter the configurations of hosted Fe Ti oxide micro-inclusions. • Intensity of the events can recrystallize micro-inclusions leading to two generations. • Stage of the events affect chemistry, oxidation, exsolution states of the inclusions. • The transformations of the micro-inclusions are examined across various scales. • Evolutions of the inclusions bias paleomagnetic signals carried by these inclusions.

LithosVol. 514-515
University of Vienna (AT), Ernst Ruska Centre (DE), Institute of Geology of Ore Deposits Petrography Mineralogy and Geochemistry (RU)
Russian Foundation for Basic Research, Austrian Science Fund, Horizon 2020 Framework Programme, HORIZON EUROPE Framework Programme
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Geomagnetism and Paleomagnetism Studies
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