Multifunctional PNN-Ni<sup>II</sup> pincer catalyst for C–C and C–N bond formation <i>via</i> alkylation, cross-coupling, and hydroamination reactions
A new Ni II pincer complex [NiCl{(PNN)-κ 3 - P,N,N }] catalyses α-alkylation of ketones, N -alkylation of anilines, Suzuki couplings, and anti-Markovnikov hydroamination of styrenes with 0.5–1 mol% loading, affording up to 99% yield under mild conditions.
Authors
- Maravanji S. Balakrishna (ORCID: https://orcid.org/0000-0003-3736-6148)
- Gazal Sabharwal
- Khilesh C. Dwivedi
Institutions
- Indian Institute of Technology Bombay (IN)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cy00718f
- Citations
- 2
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 1.07