Synthesis of multisubstituted cyclohexenes and cyclopentenes <i>via</i> cascade Michael/aldol/annulative SuFEx/β-sultone desulfonation of β-arylethenesulfonyl fluorides

γ- and β-Ketomalononitriles react with β-arylethenesulfonyl fluorides via a cascade Michael addition/aldol reaction/annulative SuFEx/β-sultone desulfonation process to produce multisubstituted cyclohexenes and cyclopentenes.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00837a
Primary Topic
Organic and Inorganic Chemical Reactions
Type
article
Field-Weighted Citation Impact
0.00

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article

Synthesis of multisubstituted cyclohexenes and cyclopentenes via cascade Michael/aldol/annulative SuFEx/β-sultone desulfonation of β-arylethenesulfonyl fluorides

Pei Xie, Zhihua Cai, Guangfen Du, Lin He et al.
Organic Chemistry Frontiers
Organic and Inorganic Chemical Reactions
article

Synthesis of multisubstituted cyclohexenes and cyclopentenes via cascade Michael/aldol/annulative SuFEx/β-sultone desulfonation of β-arylethenesulfonyl fluorides

Pei Xie, Zhihua Cai, Guangfen Du, Lin He, Fang Zhang, Qichao Zhang, Qifan Wang
article en

Abstract

γ- and β-Ketomalononitriles react with β-arylethenesulfonyl fluorides via a cascade Michael addition/aldol reaction/annulative SuFEx/β-sultone desulfonation process to produce multisubstituted cyclohexenes and cyclopentenes.

Organic Chemistry FrontiersVol. 12(22)
Shihezi University (CN)
Shihezi University
Openalex Percentile: Top 83%
Organic and Inorganic Chemical Reactions
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Synthesis of multisubstituted cyclohexenes and cyclopentenes <i>via</i> cascade Michael/aldol/annulative SuFEx/β-sultone desulfonation of β-arylethenesulfonyl fluorides — Pei Xie, Zhihua Cai, et al. · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS