Broad spin crossover in an iron(<scp>iii</scp>) Schiff base complex with a <i>cis</i>-FeN<sub>4</sub>O<sub>2</sub> coordination environment
Asymmetrical condensation of ethylenediamine with 5-bromo-2-hydroxybenzaldehyde yielded a Schiff base, ( E )-2-(((2-aminoethyl)imino)methyl)-4-bromophenol (5-Brsaen), and the reaction with Fe(NO 3 ) 3 ·9H 2 O generated the complex [Fe(5-Brsaen) 2 ]NO 3 ·CH 3 OH.
Authors
- Volker Schünemann (ORCID: https://orcid.org/0000-0002-3162-1032)
- Juraj Černák (ORCID: https://orcid.org/0000-0002-8143-1368)
- Annie K. Powell (ORCID: https://orcid.org/0000-0003-3944-7427)
- Christopher E. Anson (ORCID: https://orcid.org/0000-0001-7992-7797)
- Tim Hochdörffer (ORCID: https://orcid.org/0000-0002-8526-8289)
- Juraj Kuchár (ORCID: https://orcid.org/0000-0003-3473-7150)
- Jonas Braun (ORCID: https://orcid.org/0000-0002-2590-4546)
- Atakilt Abebe (ORCID: https://orcid.org/0000-0002-5496-664X)
- Madhu Thomas (ORCID: https://orcid.org/0000-0003-4352-5360)
- Nandakumar Kalarikkal (ORCID: https://orcid.org/0000-0002-4595-6466)
- Pascal Boulet (ORCID: https://orcid.org/0000-0001-5151-7526)
- Dawit Tesfaye (ORCID: https://orcid.org/0000-0002-0823-2039)
- Mamo Gebrezgiabher
Institutions
- Karlsruhe Institute of Technology (DE)
- Centre National de la Recherche Scientifique (FR)
- Institute of Chemistry of the Slovak Academy of Sciences (SK)
- Mahatma Gandhi University (IN)
- University of Pavol Jozef Šafárik (SK)
- University of Koblenz and Landau (DE)
- Addis Ababa Science and Technology University (ET)
- Institut Jean Lamour (FR)
- Salale University
- Bahir Dar University (ET)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nj02493e
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00