<i>N</i>-hydrazine cyclic(amino)(alkyl)carbene ruthenium complexes: synthesis and reactivity in olefin metathesis
The synthesis of a ruthenium complex containing an <i>N</i>-hydrazine cyclic(amino)(alkyl)carbene (CAAC) ligand is reported. This robust and air-stable complex demonstrates good to excellent catalytic performances under an air atmosphere in various ring-closing metathesis (RCM), ring-closing enyne metathesis (RCEYM), ring-opening cross-metathesis (ROCM), self-metathesis (SM), cross-metathesis (CM) and ethenolysis reactions.
Authors
- Thierry Roisnel (ORCID: https://orcid.org/0000-0002-6088-4472)
- Clément Casalta (ORCID: https://orcid.org/0000-0001-5826-7427)
- Marc Mauduit (ORCID: https://orcid.org/0000-0002-7080-9708)
- Angelino Doppiu (ORCID: https://orcid.org/0009-0002-0965-5444)
- Rodolphe Jazzar (ORCID: https://orcid.org/0000-0002-4156-7826)
Institutions
- Centre National de la Recherche Scientifique (FR)
- San Diego State University (US)
- Umicore (Germany) (DE)
- École Nationale Supérieure de Chimie de Rennes (FR)
- Université de Rennes (FR)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03776j
- Citations
- 1
- Primary Topic
- Synthetic Organic Chemistry Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.94