Visible light-driven regioselective <i>tert</i>-butyl peroxidation and hydroperoxidation of alkenes using TBHP

We report a visible-light-driven bisperoxidation of aryl alkenes using TBHP, enabling the regioselective synthesis of α,β-bisperoxides. This represents the first radical reaction using TBHP as source of tert -butylperoxy and hydroperoxy groups.

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Publication Details

Journal
Green Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5gc02911b
Citations
4
Primary Topic
Oxidative Organic Chemistry Reactions
Type
article
Field-Weighted Citation Impact
3.74

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article

Visible light-driven regioselective tert-butyl peroxidation and hydroperoxidation of alkenes using TBHP

Peng Zhou, Weibing Liu, Jingxing Jiang, Jiang Yan-fu et al.
4 citations
Green Chemistry
Oxidative Organic Chemistry Reactions
3.74
article

Visible light-driven regioselective tert-butyl peroxidation and hydroperoxidation of alkenes using TBHP

Peng Zhou, Weibing Liu, Jingxing Jiang, Jiang Yan-fu, Jiantao Zhang, Xian Jiang, Renhua Su
article en
4 citations

Abstract

We report a visible-light-driven bisperoxidation of aryl alkenes using TBHP, enabling the regioselective synthesis of α,β-bisperoxides. This represents the first radical reaction using TBHP as source of tert -butylperoxy and hydroperoxy groups.

Green ChemistryVol. 27(33)
Guangdong University of Petrochemical Technology (CN)
Guangdong University of Petrochemical Technology, National Natural Science Foundation of China
Openalex Percentile: Top 7%
Oxidative Organic Chemistry Reactions
3.74
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Visible light-driven regioselective <i>tert</i>-butyl peroxidation and hydroperoxidation of alkenes using TBHP — Peng Zhou, Weibing Liu, et al. · Green Chemistry (2025) | TGRS Research Map | TGRS