Chemical tuning of a double double perovskite oxide
The feasibility of chemical doping of a double double perovskite (DDPv) is demonstrated by La<sub><i>x</i></sub>Ca<sub>1-<i>x</i></sub>MnMnReO<sub>6</sub> solid solutions in which cation-site ordering is preserved to <i>x</i> ≥ 0.5 while La<sup>3+</sup>/Ca<sup>2+</sup> substitution at one site tunes magnetic properties. Each of the ∼20 DDPv's discovered by high pressure synthesis in recent years is thus a starting point for chemical tuning to discover and tune electronic and magnetic properties.
Authors
- Sean Injac (ORCID: https://orcid.org/0000-0002-4362-891X)
- Paul V. Attfield (ORCID: https://orcid.org/0000-0003-0862-2384)
- Kunlang Ji (ORCID: https://orcid.org/0000-0002-8529-9616)
- C. Ritter (ORCID: https://orcid.org/0000-0003-3674-3378)
- Azizah Almadhi
Institutions
- Institut Laue-Langevin (FR)
- University of Edinburgh (GB)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03601a
- Citations
- 1
- Primary Topic
- Magnetic and transport properties of perovskites and related materials
- Type
- article
- Field-Weighted Citation Impact
- 0.43
Funders
- Engineering and Physical Sciences Research Council
- Science and Technology Facilities Council