Facile oxidative amination with imidazole and <scp>l</scp>-histidine coordinated cobaloximes
The simple, robust, and synthetically adaptable cobaloxime core provides an ideal catalytic model for photo- and electrocatalytic H<sub>2</sub> production. Water solubility, oxygen tolerance, and acid stability make these catalysts appealing for sustainable chemistry applications. In this study, we explored cobaloximes with axial imidazole or L-histidine coordination [Co-DMG-X; imidazole, histidine] in photocatalytic hydrogen atom transfer (HAT) reactions for the synthesis of <i>N</i>-arylazoles from arenes and azoles.
Authors
- Arnab Dutta (ORCID: https://orcid.org/0000-0002-9998-6329)
- Banabir Pal (ORCID: https://orcid.org/0000-0003-2423-4373)
- Debabrata Maiti (ORCID: https://orcid.org/0000-0001-8353-1306)
- Subir Panja (ORCID: https://orcid.org/0000-0002-8682-6094)
- Santanu Ghorai (ORCID: https://orcid.org/0000-0002-4597-9289)
- Chandan Nandi (ORCID: https://orcid.org/0000-0001-8670-7370)
- Partha Pratim Manna (ORCID: https://orcid.org/0000-0003-2939-0818)
- RS Chauhan (ORCID: https://orcid.org/0000-0002-1931-3512)
Institutions
- Indian Institute of Technology Bombay (IN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02787j
- Primary Topic
- Porphyrin Metabolism and Disorders
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Council of Scientific and Industrial Research, India
- Science and Engineering Research Board