Electrochemical anilinium reduction: identifying the metastable surface intermediate on Pt and its voltage-driven decomposition to hydrogen evolution
Anilinium undergoes direct electroreduction on Pt, forming a multilayered metastable surface intermediate when adsorbed. Microelectrode voltammetry reveals voltage-driven decomposition to H 2 , and DFT shows reduced anilinium stacking on H-bound Pt.
Authors
- YongJoo Kim (ORCID: https://orcid.org/0000-0002-6037-7243)
- Dong‐Ho Seo (ORCID: https://orcid.org/0000-0003-0423-5686)
- Seung Jae Kwak (ORCID: https://orcid.org/0000-0002-9841-4134)
- Jinho Chang (ORCID: https://orcid.org/0000-0002-5572-2364)
- Cheolmin Park (ORCID: https://orcid.org/0000-0001-9750-6355)
- D.-E. Park
- Won Bo Lee (ORCID: https://orcid.org/0000-0001-7801-083X)
- Ki Min Nam (ORCID: https://orcid.org/0000-0003-1718-5876)
- Dongmin Kim (ORCID: https://orcid.org/0000-0003-4487-7069)
Institutions
- Seoul National University (KR)
- Korea University (KR)
- Hanyang University (KR)
- Pusan National University (KR)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta02666k
- Primary Topic
- Electrochemical Analysis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00