Dimethyl(methylthio)sulfonium salt triggered dithiocarbamation of alkenes with CS<sub>2</sub> and amines
In this work, a straightforward and practical four-component reaction involving alkenes, CS<sub>2</sub>, amines, and dimethyl(methylthio)sulfonium trifluoromethanesulfonate (DMTSM) is reported. This reaction enables the convenient synthesis of various <i>S</i>-alkyl dithiocarbamates in good to excellent yields. The mild reaction conditions, readily available starting materials and operational simplicity, along with numerous examples of late-stage functionalization, render this method highly attractive for organic synthesis.
Authors
- Long‐Yong Xie (ORCID: https://orcid.org/0000-0002-8932-7282)
- Leo K. Cheng (ORCID: https://orcid.org/0000-0003-2426-8987)
- Limei Duan
- Changxing Qi (ORCID: https://orcid.org/0000-0001-8596-6303)
- Ding Luo
- Sha Peng (ORCID: https://orcid.org/0000-0003-2411-6414)
- Li‐Hua Yang (ORCID: https://orcid.org/0000-0001-7106-3015)
- Shaopeng Tian (ORCID: https://orcid.org/0000-0002-5024-9651)
Institutions
- Hunan University of Science and Engineering (CN)
Publication Details
- Journal
- Organic & Biomolecular Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ob01043h
- Citations
- 1
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.94