Modular assembly of 4-trifluoromethyl-substituted 2-imino-1,3-oxathioles <i>via</i> cobalt( <scp>ii</scp> )-based metalloradical catalysis
A Co( ii )-based metalloradical-catalyzed cycloaddition of α-trifluoromethyl-α-diazoketones with isothiocyanates was developed to access 4-trifluoromethylated 2-imino-1,3-oxathioles.
Authors
- Chengxiao Liu (ORCID: https://orcid.org/0000-0002-9067-533X)
- Baiquan Wang (ORCID: https://orcid.org/0000-0003-4605-1607)
- Bin Li (ORCID: https://orcid.org/0000-0002-0145-5926)
Institutions
- Chinese Academy of Sciences (CN)
- Nankai University (CN)
- Shanghai Institute of Organic Chemistry (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00989h
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00