Theoretical insights into the mechanism and selectivities of rhodium/amine dual catalysis in alkyne–cyclopropene reassembly reactions
DFT calculations reveal the detailed mechanism and elucidate the roles of Rh and amine catalysis, as well as the origins of regio- and stereoselectivity in alkyne–cyclopropene reassembly.
Authors
- Gangbing Song (ORCID: https://orcid.org/0000-0001-5135-5555)
- Juan Li (ORCID: https://orcid.org/0000-0003-0693-3162)
- Huan Wang (ORCID: https://orcid.org/0000-0002-6759-3475)
- Keying Zhang (ORCID: https://orcid.org/0000-0002-7888-7938)
Institutions
- Jinan University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00898k
- Citations
- 1
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- National Natural Science Foundation of China