O/H Supercritical Fluid Passivation on Stacked Ge<sub>0.95</sub>Si<sub>0.05</sub> Nanosheet nFETs
O/H supercritical fluid (SCF) passivation enhances <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{I}_{\mathbf{ON}}$</tex> and reduces SS in stacked <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{Ge}_{0.95}\mathbf{Si}_{0.05}$</tex> nanosheet nFETs. With O-SCF, <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{I}_{\mathbf{ON}}$</tex> reaches <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$53\boldsymbol{\mu}\mathbf{A}$</tex> per floor at <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{V}_{\mathbf{OV}}=\mathbf{V}_{\mathbf{DS}}=0.5\mathbf{V}$</tex>, while <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$250^{\circ}\mathbf{C}$</tex> H-SCF achieves a record <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{I}_{\text{ON}}$</tex> of <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$73\boldsymbol{\mu}\mathbf{A}$</tex> per floor. O-SCF reduces oxygen vacancies in <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{Hf}_{0.2}\mathbf{Zr}_{0.8}\mathbf{O}_{2}$</tex>, while H-SCF passivates <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{D}_{\text{it}}$</tex> at the <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{Hf}_{0.2} \mathbf{Zr}_{0.8} \mathbf{O}_{2} / \mathbf{Ge}_{0.95} \mathbf{Si}_{0.05}$</tex> interface. H-SCF can outperform O-SCF, achieving improved <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{I}_{\text{ON}}$</tex> and SS due to higher diffusion coefficient and more effective passivation of H than O [1]. In addition, it does not form an interfacial layer, preserving large <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{C}_{\mathbf{OX}}$</tex>.
Authors
- B.Y. Yu
- Ting‐Chang Chang (ORCID: https://orcid.org/0000-0002-5301-6693)
- Julia Hsu
- Wei-Jen Chen (ORCID: https://orcid.org/0000-0003-1748-7743)
- Yu-Rui Chen (ORCID: https://orcid.org/0000-0002-1564-7750)
- Bo‐Wei Huang (ORCID: https://orcid.org/0000-0002-1405-8639)
- Hong‐Yi Tu (ORCID: https://orcid.org/0000-0003-1203-3574)
- Tao Chou (ORCID: https://orcid.org/0009-0003-3872-3466)
- Yi‐Chun Liu
- GuanHua Chen (ORCID: https://orcid.org/0000-0001-5015-0902)
- C. W. Liu (ORCID: https://orcid.org/0000-0002-6439-8754)
- Min-Kuan Lin
- Ding-Wei Lin
Institutions
- National Sun Yat-sen University (TW)
- National Taiwan University (TW)
Publication Details
- Published
- 2025-06-08
- DOI
- https://doi.org/10.23919/snw65111.2025.11097221
- Primary Topic
- Semiconductor materials and devices
- Type
- article
- Field-Weighted Citation Impact
- 0.00