Destabilization of ammonia borane <i>via</i> dual confinement in a cobalt-based Prussian blue analogue
The lacunar Co II [Co III (CN) 6 ] 2/3 □ 1/3 Prussian blue analogue confines ammonia borane (NH 3 BH 3 ) via a dual mechanism: with chemisorption onto coordinatively unsaturated Co 2+ sites and physisorption within the vacancies of the porous structure.
Authors
- Umit B. Demirci (ORCID: https://orcid.org/0000-0003-3616-1810)
- Fabrice Salles (ORCID: https://orcid.org/0000-0001-8069-533X)
- Jérôme Long (ORCID: https://orcid.org/0000-0002-2601-4289)
- Maëlle Cahu
- Carlos Castilla Martinez
Institutions
- École Nationale Supérieure de Chimie de Montpellier (FR)
- Centre National de la Recherche Scientifique (FR)
- Institut Universitaire de France (FR)
- Université de Montpellier (FR)
- Institut Européen des Membranes (FR)
Publication Details
- Journal
- Sustainable Energy & Fuels
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5se00758e
- Primary Topic
- Inorganic Chemistry and Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Agence Nationale de la Recherche
- Région Occitanie Pyrénées-Méditerranée