Superparamagnetic Fe<sub>3</sub>O<sub>4</sub> clusters with a wide-range size tunability

Superparamagnetic Fe<sub>3</sub>O<sub>4</sub> clusters with a tunable size over a wide range were synthesized by a polyol process. The average size of the Fe<sub>3</sub>O<sub>4</sub> clusters was controlled from 571 nm to 1210 nm only by aging Fe<sup>3+</sup> solutions before hydrolysis of Fe<sup>3+</sup> without changing the other conditions. The Fe<sub>3</sub>O<sub>4</sub> clusters had both superparamagnetic properties and high saturation magnetization per particle.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc02702k
Primary Topic
Iron oxide chemistry and applications
Type
article
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article

Superparamagnetic Fe3O4 clusters with a wide-range size tunability

Satoshi Yamabi, Shigemoto Abe, Norishige Kakegawa, Daisuke Sasaguri Daisuke Sasaguri
Chemical Communications
Iron oxide chemistry and applications
article

Superparamagnetic Fe3O4 clusters with a wide-range size tunability

Satoshi Yamabi, Shigemoto Abe, Norishige Kakegawa, Daisuke Sasaguri Daisuke Sasaguri
article en

Abstract

Superparamagnetic Fe<sub>3</sub>O<sub>4</sub> clusters with a tunable size over a wide range were synthesized by a polyol process. The average size of the Fe<sub>3</sub>O<sub>4</sub> clusters was controlled from 571 nm to 1210 nm only by aging Fe<sup>3+</sup> solutions before hydrolysis of Fe<sup>3+</sup> without changing the other conditions. The Fe<sub>3</sub>O<sub>4</sub> clusters had both superparamagnetic properties and high saturation magnetization per particle.

Chemical CommunicationsVol. 61(69)
Canon (Japan) (JP)
Openalex Percentile: Top 88%
Iron oxide chemistry and applications
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