Reversible formation of yttrium planar cyclo-P <sub>4</sub> clusters and their selective conversion: access to mixed P <sup>V</sup> /P <sup>III</sup> cyclo-P <sub>4</sub> units
A solvent-induced reversible activation of white phosphorus was achieved using a rare-earth complex for the first time, and the P 4 activation product was then readily converted into planar mixed P V /P III cyclo-P 4 clusters through an oxidation process.
Authors
- Qing You
- K. Li
- Y Li (ORCID: https://orcid.org/0000-0003-0440-0899)
- Xigeng Zhou (ORCID: https://orcid.org/0000-0003-2948-9930)
- Shanlin Duan (ORCID: https://orcid.org/0000-0002-2774-3328)
- Jie Zhang (ORCID: https://orcid.org/0000-0002-9941-1568)
- Junliang Zhang (ORCID: https://orcid.org/0000-0002-2630-4534)
- Zihao Ye (ORCID: https://orcid.org/0000-0002-6450-8108)
- Keyu Han
Institutions
- Fudan University (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi01220a
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00