Glass transition-induced luminescence in ZIF-62
We reported that ZIF-62 glass exhibits enhanced luminescence upon glass transition, contrasting with the crystalline phase fluorescence quenching caused by ordered ligand arrangement. Theoretical simulations combining <i>ab initio</i> molecular dynamics and quantum mechanical calculations reveal specific configurations in the glassy state with intensified emission, which are corroborated by experiments.
Authors
- S. F. Yu (ORCID: https://orcid.org/0000-0003-0354-3767)
- Yichao Lin (ORCID: https://orcid.org/0000-0001-6851-396X)
- Ziqi Tian (ORCID: https://orcid.org/0000-0001-5667-597X)
- Haitao Hu (ORCID: https://orcid.org/0000-0001-8496-5704)
- Wen Yang (ORCID: https://orcid.org/0000-0002-3776-6566)
Institutions
- Chinese Academy of Sciences (CN)
- University of Chinese Academy of Sciences (CN)
- Ningbo Institute of Industrial Technology (CN)
- Taiyuan University of Science and Technology (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01504a
- Citations
- 1
- Primary Topic
- Lanthanide and Transition Metal Complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.52
Funders
- National Natural Science Foundation of China
- Youth Innovation Promotion Association of the Chinese Academy of Sciences
- Ministry of Industry and Information Technology of the People's Republic of China
- Youth Innovation Promotion Association