A detailed study on the effects of adsorbed water molecules on proton conduction in a metal–organic framework
We demonstrate the proton-conductive properties of Zr-BPT, having one-dimensional pores. The MOF shows superprotonic conductivity of 3.6 × 10<sup>-4</sup> S cm<sup>-1</sup> at room temperature (25 °C). The conduction mechanism was discussed with the relationship among the structure, conductive properties, and adsorption behaviour.
Authors
- Keisuke Fujihira
- Masaaki Sadakiyo (ORCID: https://orcid.org/0000-0001-5359-3581)
- Kenichi Kato (ORCID: https://orcid.org/0000-0001-5348-5521)
- Kyoko Shiraishi
- Mitsuki Kabaya
Institutions
- Tokyo University of Science (JP)
- SPring-8 (JP)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt01395j
- Citations
- 4
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 2.15
Funders
- RIKEN